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Phys. Rev. B 74, 085103 (2006) [11 pages]

X-ray 2p photoelectron and Lalpha resonant x-ray emission spectra of the 3d metals in Ni2MnZ (Z=In,Sn,Sb) Heusler alloys

M. V. Yablonskikh,1,2 J. Braun,3 M. T. Kuchel,3 A. V. Postnikov,2 J. D. Denlinger,4 E. I. Shreder,2 Y. M. Yarmoshenko,2 M. Neumann,5 and A. Moewes1
1Department of Physics and Engineering Physics, University of Saskatchewan, Saskatoon, Canada S7N 5E2
2Institute of Metal Physics, Russian Academy of Sciences, Ural Division, 620219 Yekaterinburg GSP-170, Russia
3Physikalisches Institut, Westfälische-Wilhelms Universität Münster, Wilhelm-Klemm-Str. 10, D-48149 Münster, Germany
4Lawrence Berkeley National Laboratory, Berkeley, California 94720
5Department of Physics, Osnabrück University, D-49069 Osnabrück, Germany

Received 21 March 2006; published 1 August 2006

Magnetic and chemical bonding effects in Heusler alloys Ni2MnIn, Ni2MnSn, and Ni2MnSb were studied by soft x-ray spectroscopy. Exchange splitting detected in Mn 2p core-level x-ray photoelectron spectra and an increase of the Mn Lbeta/Lalpha intensity ratio in nonresonant x-ray emission spectra show that atomic magnetic moment at Mn is higher than that of pure metal. Spin polarized density of states calculations and comparative analysis of Mn and Ni Lalpha resonant x-ray emission spectra (RXES) demonstrate that the spin splitting in Mn 3d shell is larger than in Ni 3d shell. The d-d transitions observed in Lalpha RXES of Mn and Ni are suggested to be more intensive for Mn than for Ni valence electrons when initiated by off-resonant excitations. Experimental findings are supported by photoelectron spectra calculations and developed two-step model of resonant x-ray emission. The interplay between Mn Lalpha RXES and calculated magnetic moments of Mn atoms in alloys as a function of the type of Z element is discussed.

©2006 The American Physical Society

URL: http://link.aps.org/doi/10.1103/PhysRevB.74.085103
DOI: 10.1103/PhysRevB.74.085103
PACS: 78.70.En; 75.50.Cc; 71.20.-b
  • 78.70.En
    X-ray emission spectra and fluorescence (condensed matter)
  • 75.50.Cc
    Ferromagnetism of nonferrous metals and alloys
  • 71.20.-b
    Electronic structure of crystalline solids
  • YEAR: 2006
KEYWORDS: nickel alloys, manganese alloys, indium alloys, tin alloys, antimony alloys, X-ray photoelectron spectra, X-ray emission spectra, exchange interactions (electron), magnetic moments, electron spin polarisation, electronic density of states, valence bands

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