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Phys. Rev. Lett. 103, 187802 (2009) [4 pages]

Thickness Dependent Phase Behavior of Antiferroelectric Liquid Crystal Films

LiDong Pan,1 Shun Wang,1 C. S. Hsu,2 and C. C. Huang1
1School of Physics and Astronomy, University of Minnesota, Minneapolis, Minnesota 55455, USA
2Department of Applied Chemistry, National Chiao Tung University, Hsinchu 30050, Taiwan

Received 8 June 2009; published 30 October 2009

Free standing films of a liquid crystal compound with simple surface enhanced order were studied. The resultant phase diagram demonstrates that (1) the short helical pitch smectic-C<sub>alpha</sub><sup>*</sup> phase disappears below a film thickness of 10 layers, and (2) the temperature window of a distorted 4 layer smectic-C<sub>FI2</sub><sup>*</sup> phase increases dramatically upon decreasing film thickness. The experimental findings were attributed to the reduced dimensionality and enhanced surface effects in thin films. The results of the smectic-C<sub>alpha</sub><sup>*</sup> phase are consistent with what have been reported for helically ordered magnetic thin films, with a noticeable difference due to the opposite effect of the surface on ordering in the two systems.

©2009 The American Physical Society

URL: http://link.aps.org/doi/10.1103/PhysRevLett.103.187802
DOI: 10.1103/PhysRevLett.103.187802
PACS: 61.30.Hn; 64.70.M-; 77.84.Nh
  • 61.30.Hn
    Surface phenomena in liquid crystals
  • 64.70.M-
    Transitions in liquid crystals
  • 77.84.Nh
    Dielectric, piezoelectric, and ferroelectric liquids, emulsions, and suspensions; liquid crystals
  • YEAR: 2009

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