Phys. Rev. Lett. 103, 187802 (2009) [4 pages]
Thickness Dependent Phase Behavior of Antiferroelectric Liquid Crystal Films
Abstract
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LiDong Pan, 1 Shun Wang, 1 C. S. Hsu, 2 and C. C. Huang11School of Physics and Astronomy, University of Minnesota, Minneapolis, Minnesota 55455, USA
2Department of Applied Chemistry, National Chiao Tung University, Hsinchu 30050, Taiwan
Received 8 June 2009; published 30 October 2009
Free standing films of a liquid crystal compound with simple surface enhanced order were studied. The resultant phase diagram demonstrates that (1) the short helical pitch smectic-C phase disappears below a film thickness of 10 layers, and (2) the temperature window of a distorted 4 layer smectic-C phase increases dramatically upon decreasing film thickness. The experimental findings were attributed to the reduced dimensionality and enhanced surface effects in thin films. The results of the smectic-C phase are consistent with what have been reported for helically ordered magnetic thin films, with a noticeable difference due to the opposite effect of the surface on ordering in the two systems.
©2009 The American Physical Society
| URL: |
http://link.aps.org/doi/10.1103/PhysRevLett.103.187802
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| DOI: |
10.1103/PhysRevLett.103.187802 |
| PACS: |
61.30.Hn;
64.70.M-;
77.84.Nh
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