Review of Scientific Instruments
Search:
   
 
 
 
Previous Article
A study of the performance of an ion shutter for drift tubes in atmospheric pressure ion mobility spectrometry: Computer models and experimental findings
Ion mobility spectra are initiated when ions, derived from a sample, are pulsed or injected through ion shutters into a drift region. The effect on signal intensity from electric fields arising from t...
Next Article
Velocity map imaging using an in-vacuum pixel detector
The use of a new type in-vacuum pixel detector in velocity map imaging (VMI) is introduced. The Medipix2 and Timepix semiconductor pixel detectors (256×256 square pixels, 55×55  ...

Large-area imager of hydrogen leaks in fuel cells using laser-induced breakdown spectroscopy

Rev. Sci. Instrum. 80, 103104 (2009); doi:10.1063/1.3244089

Published 13 October 2009

You are not logged in to this journal. Log in

M. Hori,1,2 R. S. Hayano,2 M. Fukuta,3 T. Koyama,3 H. Nobusue,3 and J. Tanaka3
1Max-Planck Institut für Quantenoptik, Hans-Kopfermann-Strasse 1, D-85748 Garching, Germany
2Department of Physics, University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan
3Automobile R&D Center, Honda R&D Corporation, 4630 Oaza, Shimo-Takanezawa, Haga-Machi, Haga-gun, Tochigi-ken 329-1495, Japan

We constructed a simple device, which utilized laser-induced breakdown spectroscopy to image H2 gas leaking from the surfaces of hydrogen fuel cells to ambient air. Nanosecond laser pulses of wavelength lambda=532  nm emitted from a neodymium-doped yttrium aluminum garnet laser were first compressed to a pulse length Deltat<1  ns using a stimulated Brillouin backscattering cell. Relay-imaging optics then focused this beam onto the H2 leak and initiated the breakdown plasma. The Balmer-alpha (H-alpha) emission that emerged from this was collected with a 2-m-long macrolens assembly with a 90-mm-diameter image area, which covered a solid angle of ~1×10−3pi steradians seen from the plasma. The H-alpha light was isolated by two 100-mm-diameter interference filters with a 2 nm bandpass, and imaged by a thermoelectrically cooled charge-coupled device camera. By scanning the position of the laser focus, the spatial distribution of H2 gas over a 90-mm-diameter area was photographed with a spatial resolution of <=5  mm. Photoionization of the water vapor in the air caused a strong H-alpha background. By using pure N2 as a buffer gas, H2 leaks with rates of <1  cc/min were imaged. We also studied the possibilities of detecting He, Ne, or Xe gas leaks. ©2009 American Institute of Physics
History: Received 7 April 2009; accepted 14 September 2009; published 13 October 2009
Permalink: http://link.aip.org/link/?RSINAK/80/103104/1

Submit to JRSE

BUY THIS ARTICLE   (US$24)
Download PDF (451 kB) View Cart

KEYWORDS and PACS

Keywords
PACS
  • 82.47.-a
    Applied electrochemistry
  • 42.55.Px
    Semiconductor lasers; laser diodes
  • 42.79.Pw
    Imaging detectors and sensors
  • YEAR: 2009

RELATED DATABASES


To view database links for this article,
you need to log in.
To view database links for this article,
you need to log in.

PUBLICATION DATA

ISSN:
0034-6748 (print)   1089-7623 (online)
Publisher:
AIP is a member of CrossRef AIP

REFERENCES (73)

For access to fully linked references, you need to log in. For access to fully linked references, you need to Log in.
  1. R. G. Seller and D. Wang, “Assessment of Remote Sensing Technologies for Location of Hydrogen and Helium Leaks”, NAG10-0290 Phase 1 Final Report, Florida Space Inst., 2000.
  2. C. G. Morgan, Rep. Prog. Phys. 38, 621 (1975).
  3. P. K. Kennedy, IEEE J. Quantum Electron. 31, 2241 (1995).
  4. D. A. Rusak, B. C. Castle, B. W. Smith, and J. D. Winefordner, Crit. Rev. Anal. Chem. 27, 257 (1997).
  5. L. Dudragne, Ph. Adam, and J. Amouroux, Appl. Spectrosc. 52, 1321 (1998).
  6. E. Tognoni, V. Palleschi, M. Corsi, and G. Cristoforetti, Spectrochim. Acta, Part A 57B, 1115 (2002).
  7. V. Sturm and R. Noll, Appl. Opt. 42, 6221 (2003).
  8. G. Colonna, L. D. Pietanza, and M. Capitelli, Spectrochim. Acta, Part A 56B, 587 (2001).
  9. A. J. Ball, V. Hohreiter, and D. W. Hahn, Appl. Spectrosc. 59, 348 (2005).
  10. A. Sircar, R. K. Dwivedi, and R. K. Thareja, Appl. Phys. B: Lasers Opt. 63, 623 (1996).
  11. T. X. Phuoc, Opt. Commun. 175, 419 (2000).
  12. J. -L. Beduneau and Y. Ikeda, J. Quant. Spectrosc. Radiat. Transf. 84, 123 (2004).
  13. M. LuVan, G. Mainfray, C. Manus, and I. Tugov, Phys. Rev. A 7, 91 (1973).
  14. B. Wolff, H. Rottke, D. Feldmann, and K. H. Welge, Z. Phys. D: At., Mol. Clusters 10, 35 (1988).
  15. A. Zavriyev, P. H. Bucksbaum, H. G. Muller, and D. W. Schumacher, Phys. Rev. A 42, 5500 (1990).
  16. Ya. B. Zel'dovich and Yu. P. Raizer, Sov. Phys. JETP 20, 772 (1965).
  17. N. Kroll and K. M. Watson, Phys. Rev. A 5, 1883 (1972).
  18. G. H. Canavan and R. E. Nielsen, Appl. Phys. Lett. 22, 409 (1973).
  19. D. E. Lencioni, Appl. Phys. Lett. 23, 12 (1973).
  20. D. C. Smith, J. Appl. Phys. 48, 2217 (1977).
  21. Y. -L. Chen, J. W. L. Lewis, and C. Parigger, J. Quant. Spectrosc. Radiat. Transf. 67, 91 (2000).
  22. I. G. Dors and C. G. Parigger, Appl. Opt. 42, 5978 (2003).
  23. C. Parigger, D. H. Plemmons, and J. W. L. Lewis, Appl. Opt. 34, 3325 (1995).
  24. S. M. Adler-Golden, N. Goldstein, F. Bien, M. W. Matthew, M. E. Gersh, W. K. Cheng, and F. W. Adams, Appl. Opt. 31, 831 (1992).
  25. P. R. Régnier and J. P.-E. Taran, Appl. Phys. Lett. 23, 240 (1973).
  26. G. M. Mikheev, A. Y. Popov, and T. N. Mogileva, Instrum. Exp. Tech. 48, 671 (2005).
  27. H. Ninomiya, S. Yaeshima, K. Ichikawa, and T. Fukuchi, Opt. Eng. 46, 094301 (2007).
  28. Y. Oki, S. Nakazono, Y. Nonaka, and M. Maeda, Opt. Lett. 25, 1040 (2000).
  29. Yu. O. Barmenkov, A. Ortigosa-Blanch, A. Diez, J. L. Cruz, and M. V. Andrés, Opt. Lett. 29, 2461 (2004).
  30. J. Villatoro and D. Monzón-Hernández, Opt. Express 13, 5087 (2005).
  31. S. Schiemann, W. Ubachs, and W. Hogervorst, IEEE J. Quantum Electron. 34, 407 (1998).
  32. D. Neshev, I. Velchev, W. A. Majewski, W. Hogervorst, and W. Ubachs, Appl. Phys. B: Lasers Opt. 68, 671 (1999).
  33. M. Hori and K. Hanke, Nucl. Instrum. Methods Phys. Res. A 588, 359 (2008).
  34. S. S. Mao, X. Mao, R. Greif, and R. E. Russo, Appl. Phys. Lett. 76, 31 (2000).
  35. S. S. Mao, X. Mao, R. Greif, and R. E. Russo, Appl. Phys. Lett. 77, 2464 (2000).
  36. M. Hori, J. Eades, R. S. Hayano, T. Ishikawa, J. Sakaguchi, E. Widmann, H. Yamaguchi, H. A. Torii, B. Juhász, D. Horváth, and T. Yamazaki, Phys. Rev. Lett. 87, 093401 (2001).
  37. M. Hori, J. Eades, R. S. Hayano, T. Ishikawa, W. Pirkl, E. Widmann, H. Yamaguchi, H. A. Torii, B. Juhász, D. Horváth, and T. Yamazaki, Phys. Rev. Lett. 91, 123401 (2003).
  38. M. Hori, A. Dax, J. Eades, K. Gomikawa, R. S. Hayano, N. Ono, W. Pirkl, E. Widmann, H. A. Torii, B. Juhász, D. Barna, and D. Horváth, Phys. Rev. Lett. 96, 243401 (2006).
  39. M. Hori, R. S. Hayano, E. Widmann, and H. A. Torii, Opt. Lett. 28, 2479 (2003).
  40. M. Hori and A. Dax, Opt. Lett. 34, 1273 (2009).
  41. F. E. Wagstaff, J. Am. Ceram. Soc. 51, 449 (1968).
  42. P. P. Bihuniak, J. Am. Ceram. Soc. 66, c188 (1983).
  43. V. J. Fratello, J. F. Hays, and D. Turnbull, J. Appl. Phys. 51, 4718 (1980).
  44. B. C. Stuart, M. D. Feit, A. M. Rubenchik, B. W. Shore, and M. D. Perry, Phys. Rev. Lett. 74, 2248 (1995).
  45. D. W. Camp, M. R. Kozlowski, L. M. Sheehan, M. A. Nichols, M. Dovik, R. G. Raether, and I. M. Thomas, Proc. SPIE 3244, 356 (1998).
  46. C. W. Carr, H. B. Radousky, A. M. Rubenchik, M. D. Feit, and S. G. Demos, Phys. Rev. Lett. 92, 087401 (2004).
  47. A. A. Said, T. Xia, A. Dogariu, D. J. Hagan, M. J. Soileau, E. W. Van Stryland, and M. Mohebi, Appl. Opt. 34, 3374 (1995).
  48. K. Yoshida, N. Kuzuu, T. Jitsuno, H. Yoshida, and T. Kamimura, Proc. SPIE 3492, 196 (1999).
  49. T. Kamimura, S. Akamatsu, H. Horibe, H. Shiba, S. Motokoshi, T. Sakamoto, T. Jitsuno, T. Okamato, and K. Yoshida, Jpn. J. Appl. Phys., Part 2 43, L1229 (2004).
  50. N. Kuzuu, K. Yoshida, K. Ochi, Y. Tsuboi, T. Kamimura, H. Yoshida, and Y. Namba, Jpn. J. Appl. Phys., Part 1 43, 2547 (2004).
  51. T. Kamimura, S. Motokoshi, T. Sakamoto, T. Jitsuno, H. Shiba, S. Akamatsu, H. Horibe, T. Okamoto, and K. Yoshida, Proc. SPIE 5647, 187 (2005).
  52. K. H. Kurniawan, T. J. Lie, M. M. Suliyanti, M. Pardede, S. N. Abdulmadjid, K. Kagawa, and M. O. Tjia, J. Appl. Phys. 105, 013301 (2009).
  53. M. Ramli, K. Kagawa, S. N. Abdulmadjid, N. Idris, W. S. Budi, M. A. Marpaung, K. H. Kurniawan, T. J. Lie, M. M. Suliyanti, R. Hedwig, M. Pardede, Z. S. Lie, and M. O. Tjia, Appl. Phys. B: Lasers Opt. 86, 729 (2007).
  54. N. C. Das, Appl. Opt. 30, 3589 (1991).
  55. N. Xu and V. Majidi, Appl. Spectrosc. 47, 1134 (1993).
  56. J. E. Carranza, E. Gibb, B. W. Smith, D. W. Hahn, and J. D. Winefordner, Appl. Opt. 42, 6016 (2003).
  57. M. Sabsabi, R. Héon, and L. St-Onge, Spectrochim. Acta, Part B 60, 1211 (2005).
  58. K. L. Bell, A. Hibbert, and R. P. Stafford, Phys. Scr. 52, 240 (1995).
  59. W. L. Wiese, M. W. Smith, and B. M. Glennon, National Standard Reference Data Series, National Bureau of Standards 4, Washington, 1966.
  60. J. E. Hansen and W. Persson, Phys. Scr. 36, 602 (1987).
  61. W. Whaling, W. H. C. Anderson, M. T. Carle, J. W. Brault, and H. A. Zarem, J. Res. Natl. Inst. Stand. Technol. 107, 149 (2002).
  62. E. S. Chang, W. G. Schoenfeld, E. Biémont, P. Quinet, and P. Palmeri, Phys. Scr. 49, 26 (1994).
  63. A. Sasoh, T. Ohtani, and K. Mori, Phys. Rev. Lett. 97, 205004 (2006).
  64. C. A. Henry, P. K. Diwakar, and D. W. Hahn, Spectrochim. Acta, Part B 62, 1390 (2007).
  65. M. R. Joseph, N. Xu, and V. Majidi, Spectrochim. Acta, Part B 49, 89 (1994).
  66. F. Leis, W. Sdorra, J. B. Ko, and K. Niemax, Mikrochim. Acta 98, 185 (1989).
  67. Y. Iida, Spectrochim. Acta, Part B 45, 1353 (1990).
  68. W. Sdorra and K. Niemax, Mikrochim. Acta 107, 319 (1992).
  69. R. Wisbrun, I. Schechter, R. Niessner, H. Schröder, and K. L. Kompa, Anal. Chem. 66, 2964 (1994).
  70. T. L. Thiem, R. H. Salter, J. A. Gardner, Y. I. Lee, and J. Sneddon, Appl. Spectrosc. 48, 58 (1994).
  71. D. E. Kim, K. J. Yoo, H. K. Park, K. J. Oh, and D. W. Kim, Appl. Spectrosc. 51, 22 (1997).
  72. M. Hori, J. Eades, R. S. Hayano, W. Pirkl, E. Widmann, H. Yamaguchi, H. A. Torii, B. Juhász, D. Horváth, K. Suzuki, and T. Yamazaki, Phys. Rev. Lett. 94, 063401 (2005).
  73. M. Hori, J. Eades, R. S. Hayano, T. Ishikawa, J. Sakaguchi, T. Tasaki, E. Widmann, H. Yamaguchi, H. A. Torii, B. Juhasz, D. Horvath, and T. Yamazaki, Phys. Rev. Lett. 89, 093401 (2002).

CITING ARTICLES

For access to citing articles, you need to log in.
For access to citing articles, you need to Log in.