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The single donator-single acceptor hydrogen bonding structure in water probed by Raman spectroscopy

Source: J. Chem. Phys. 132, 054507 (2010); doi:10.1063/1.3308496

Published 4 February 2010

KEYWORDS and PACS
Keywords
PACS
  • 33.20.Fb
    Raman and Rayleigh molecular spectra
  • 33.15.Fm
    Molecular bond strengths, dissociation energies
  • 33.20.Tp
    Vibrational analysis (molecular spectra)
  • 34.70.+e
    Charge transfer (atoms and molecules)
  • YEAR: 2010
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PUBLICATION DATA
ISSN:
1553-9628 (online)
Publisher:
AIP is a member of CrossRef AIP
Qiang Sun
The School of Earth and Space Sciences, Peking University, 100871, China
In this work, the Raman spectra of aqueous C12E5 solutions are recorded and utilized to demonstrate the existence of single donator-single acceptor (DA) hydrogen bonding in water. From Raman OH stretching bands of aqueous C12E5 solutions, the relative intensity of 3430  cm−1 subband increases with C12E5 concentrations. For confined water, the DA hydrogen bonding can be expected to be the important hydrogen bonding species. Therefore, the 3430  cm−1 component can be ascribed to OH vibration engaged in DA hydrogen bonding. This is in agreement with our recent explanation on Raman OH stretching band of water. For water at ambient conditions, the double donor-double acceptor (DDAA) and DA should be the dominant hydrogen bonding species, the ratio of DDAA to DA can be approximately to be 0.75:1, and the mean hydrogen bonding can be determined to be 2.75. ©2010 American Institute of Physics
History: Received 8 September 2009; accepted 13 January 2010; published 4 February 2010
Permalink: http://link.aip.org/link/?JCPSA6/132/054507/1

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