Possible hydrogen doping and enhancement of Tc (=35 K) in a LaFeAsO-based superconductor
Source: Appl. Phys. Lett. 96, 072514 (2010); doi:10.1063/1.3319508
Published 19 February 2010
KEYWORDS and PACS
cerium compounds,
doping,
high-temperature superconductors,
hydrogen,
iron compounds,
lanthanum compounds,
lattice constants,
oxygen compounds,
praseodymium compounds,
proton magnetic resonance,
superconducting transition temperature
- 74.62.Dh
Effects of crystal defects, doping and substitution on superconducting transition temperature - 61.72.up
Doping and impurity implantation in other materials - 76.60.-k
Nuclear magnetic resonance and relaxation (condensed matter) - 74.81.-g
Inhomogeneous superconductors and superconducting systems - 74.10.+v
Occurrence of superconductivity - YEAR: 2010
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PUBLICATION DATA
We report that the incorporation of hydroxide ions (OH)− significantly enhances the superconducting transition temperature (Tc) in the LnFeAsO-based superconductors (Ln1111: Ln=La, Ce, and Pr). For La1111, Tc of the (OH)− incorporated sample synthesized using high-pressure technique becomes 35 K, which is higher by 7 K than the typical optimally doped La1111 superconductors. Similar enhancement in Tc is also observed for Ce1111 and Pr1111. 1H-NMR measurement have confirmed the existence of hydrogen atoms in the samples. Accompanying the (OH)− incorporation, the lattice parameters are largely contracted, down to the values which have never been attained by any other dopings/substitutions.
©2010 American Institute of Physics
| History: | Received 27 December 2009; accepted 21 January 2010; published 19 February 2010 |
| Permalink: |
http://link.aip.org/link/?APPLAB/96/072514/1 |
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