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Mode-dependent dispersion in Raman line shapes: Observation and implications from ultrafast Raman loss spectroscopy

Source: J. Chem. Phys. 133, 024505 (2010); doi:10.1063/1.3464332

Published 13 July 2010

KEYWORDS and PACS
Keywords
PACS
  • 33.20.Fb
    Raman and Rayleigh molecular spectra
  • 52.38.Bv
    Rayleigh scattering; stimulated Brillouin and Raman scattering in plasmas
  • 33.15.Mt
    Molecular rotation, vibration, and vibration-rotation constants
  • 33.50.Dq
    Molecular fluorescence and phosphorescence spectra
  • 07.57.Ty
    Infrared spectrometers, auxiliary equipment, and techniques
  • 33.70.Jg
    Molecular line and band widths, shapes, and shifts
  • 33.70.Ca
    Molecular oscillator and band strengths, lifetimes, transition moments, and Franck-Condon factors
  • YEAR: 2010
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PUBLICATION DATA
ISSN:
1553-9601 (online)
Publisher:
AIP is a member of CrossRef AIP
S. Umapathy, B. Mallick, and A. Lakshmanna
Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore 560012, India
Ultrafast Raman loss spectroscopy (URLS) enables one to obtain the vibrational structural information of molecular systems including fluorescent materials. URLS, a nonlinear process analog to stimulated Raman gain, involves a narrow bandwidth picosecond Raman pump pulse and a femtosecond broadband white light continuum. Under nonresonant condition, the Raman response appears as a negative (loss) signal, whereas, on resonance with the electronic transition the line shape changes from a negative to a positive through a dispersive form. The intensities observed and thus, the Franck–Condon activity (coordinate dependent), are sensitive to the wavelength of the white light corresponding to a particular Raman frequency with respect to the Raman pump pulse wavelength, i.e., there is a mode-dependent response in URLS. ©2010 American Institute of Physics
History: Received 31 October 2008; accepted 24 June 2010; published 13 July 2010
Permalink: http://link.aip.org/link/?JCPSA6/133/024505/1

REFERENCES (41)

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  1. K. H. Wong, W. L. Ho, and W. L. Tsui, J. Raman Spectrosc. 23, 479 (1992).
  2. M. Yoshizawa, Y. Hattori, and T. Kobayashi, Phys. Rev. B 49, 13259 (1994).
  3. M. Yoshizawa and M. Kurosawa, Phys. Rev. A 61, 013808 (1999).
  4. F. S. Rondonuwu, Y. Watanabe, J. P. Zhang, K. Furuichi, and Y. Koyama, Chem. Phys. Lett. 357, 376 (2002).
  5. D. W. McCamant, P. Kukura, and R. A. Mathies, Appl. Spectrosc. 57, 1317 (2003).
  6. S. M. Jin, Y. J. Lee, J. Ku, and S. K. Kim, Bull. Korean Chem. Soc. 25, 1829 (2004).
  7. S. Laimgruber, H. Schachenmayr, B. Schmidt, W. Zinth, and P. A. Gilch, Appl. Phys. B 85, 557 (2006).
  8. B. Mallick, A. Lakshmanna, V. Radhalakshmi, and S. Umapathy, Curr. Sci. 95, 1551 (2008).
  9. S. Umapathy, A. Lakshmanna, and B. Mallick, J. Raman Spectrosc. 40, 235 (2009).
  10. A. Lakshmanna, B. Mallick, and S. Umapathy, Curr. Sci. 97, 210 (2009).
  11. G. Seifert, T. Patzlaff, and H. Graener, Vib. Spectrosc. 23, 219 (2000).
  12. O. An, W. Zinth, and P. Gilch, Opt. Commun. 202, 209 (2002).
  13. A. C. Albrecht, J. Chem. Phys. 34, 1476 (1961)
    14. A. C. Albrecht and M. C. Hutley, ibid. 55, 4438 (1971)
    R. J. H. Clark and T. J. Dines, Angew. Chem., Int. Ed. Engl. 25, 131 (1986)
    A. B. Myers, Acc. Chem. Res. 30, 519 (1997)
    Chem. Rev. (Washington, D.C.) 96, 911 (1996).
  14. N. Biswas and S. Umapathy, J. Chem. Phys. 107, 7849 (1997).
  15. N. Biswas and S. Umapathy, Chem. Phys. Lett. 236, 24 (1995)
    16. J. Raman Spectrosc. 32, 471 (2001).
  16. N. Biswas and S. Umapathy, J. Chem. Phys. 118, 5526 (2003).
  17. P. Chowdary and S. Umapathy, J. Raman Spectrosc. 41, 310 (2010)
    18. 39, 1538 (2008).
  18. R. R. Frontiera, S. Shim, and R. A. Mathies, J. Chem. Phys. 129, 064507 (2008).
  19. Z. Sun, J. Lu, D. H. Ahnag, and S. -Y. Lee, J. Chem. Phys. 128, 144114 (2008).
  20. W. M. Tolles, J. W. Nibler, J. R. McDonald, and A. B. Harvey, Appl. Spectrosc. 31, 253 (1977).
  21. J. Nestor, T. G. Spiro, and G. Klauminzer, Proc. Natl. Acad. Sci. U.S.A. 73, 3329 (1976).
  22. J. P. Haushalter and M. D. Morris, Anal. Chem. 53, 21 (1981).
  23. S. Saikan, N. Hashimoto, T. Kushida, and K. Namba, J. Chem. Phys. 82, 5409 (1985).
  24. M. Takayanagi, H. Hamaguchi, and M. Tasumi, J. Chem. Phys. 89, 3945 (1988).
  25. H. Lotem, R. T. Lynch, Jr., and N. Bloembergen, Phys. Rev. A 14, 1748 (1976).
  26. L. Angeloni, G. Smulevich, and M. P. Marzocchi, J. Raman Spectrosc. 8, 305 (1979).
  27. We thank one of the referees for the suggestion.
  28. R. J. Gordon and S. A. Rice, Annu. Rev. Phys. Chem. 48, 601 (1997).
  29. T. Elsaesser and W. Kaiser, Annu. Rev. Phys. Chem. 42, 83 (1991).
  30. H. Hamaguchi and T. L. Gustafson, Annu. Rev. Phys. Chem. 45, 593 (1994).
  31. I. K. Lednev, T. -Q. Ye, P. Matousek, M. Towrie, P. Foggi, F. V. R. Neuwahl, S. Umapathy, R. E. Hester, and J. N. Moore, Chem. Phys. Lett. 290, 68 (1998).
  32. Y. -C. Lu, E. W.-G. Diau, and H. Rau, J. Phys. Chem. A 109, 2090 (2005).
  33. F. O. Koller, C. Sobotta, T. E. Schrader, T. Cordes, W. J. Schreier, A. Sieg, and P. Gilch, Chem. Phys. 341, 258 (2007).
  34. A. Pugžlys, H. P. den Hartog, A. Baltuška, M. S. Pshenichnikov, S. Umapathy, and D. A. Wiersma, J. Phys. Chem. A 105, 11407 (2001).
  35. P. J. Reid, S. Alex, W. Jarzeba, R. E. Schlief, A. E. Johnson, and P. F. Barbara, Chem. Phys. Lett. 229, 93 (1994).
  36. P. J. Reid and P. F. Barbara, J. Phys. Chem. 99, 3554 (1995).
  37. A. E. Bragg and B. J. Schwartz, J. Phys. Chem. A 112, 3530 (2008).
  38. J. Z. Zhang, E. J. Hellel, D. Huber, and D. G. Imre, J. Phys. Chem. 95, 6129 (1991).
  39. Y. -L. Li, C. W. Lee, K. H. Leung, G. Z. He, and D. L. Phillips, Mol. Phys. 100, 2659 (2002).
  40. S. Yoon, R. J. Holiday, and F. F. Crim, J. Phys. Chem. B 109, 8388 (2005).
  41. M. Olivucci and F. Santoro, Angew. Chem., Int. Ed. 47, 6322 (2008).

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