Journal of Applied Physics, 15 November 2008
J. Appl. Phys. 104, 103116 (2008) (7 pages)
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Testing the effect of surface coatings on alkali atom polarization lifetimes

S. J. Seltzer,1 D. M. Rampulla,2 S. Rivillon-Amy,3 Y. J. Chabal,3 S. L. Bernasek,2 *and M. V. Romalis1

1Department of Physics, Princeton University, Princeton, New Jersey 08544, USA
2Department of Chemistry, Princeton University, Princeton, New Jersey 08544, USA
3Laboratory for Surface Modification, Rutgers University, Piscataway, New Jersey 08854, USA

(Received: 29 May 2008; accepted: 31 July 2008; published online: 24 November 2008)

The evaluation of different surface coatings used in alkali metal atomic magnetometers is necessary for the improvement of sensitivity of these devices. A method to measure the polarization lifetime of alkali atoms in the region between substrates with different coatings was developed to determine the effectiveness of the coating at preserving alkali spin polarization as well as chemical compatibility and high-temperature stability. Multiple coatings can be compared under identical experimental conditions, using an experimental geometry that allows surface characterization before and after evaluation of the polarization lifetime. Multilayered, cross-linked octadecyltrichlorosilane films, alkyltrichlorosilane monolayers, and octadecylphosphonic acid monolayers were evaluated using this approach. ©2008 American Institute of Physics


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