The Journal of Chemical Physics, 1 March 2005
J. Chem. Phys. 122, 097101 (2005) (3 pages)
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Comment on "Silver nanoparticle array structures that produce remarkably narrow plasmon line shapes" [J. Chem. Phys. 120, 10871 (2004)]

Vadim A. Markel

Department of Radiology, University of Pennsylvania, Philadelphia, Pennsylvania 19104

(Received: 4 November 2004; accepted: 20 December 2004; published online: 1 March 2005)

In this Comment I discuss two incorrect statements which were made in the paper "Silver nanoparticle array structures that produce remarkably narrow plasmon line shapes" [J. Chem. Phys.130, 10871 (2004)] by Zou, Janel, and Schatz (ZJS). The first statement is about the use of quasistatic approximation in my earlier work on the similar subject, and the second statement concerns the possibility of exact cancellation of radiative relaxation in periodical chains of nanoparticles. The relationship between the quasistatic approximation, the dipole approximation, and the approximation due to Doyle [Phys. Rev. B39, 9852 (1989)] which was used by ZJS is clarified. It is shown that the exact cancellation of radiative relaxation cannot take place in the particular geometry considered by ZJS. ©2005 American Institute of Physics


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