The Physics Teacher, Vol. 41, No. 6, pp. 345–350, September 2003
©2003 American Association of Physics Teachers. All rights reserved.
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Secular Equilibrium Experiment

In a radioactive decay series in which a parent nuclide (subscript 1) decays into a daughter nuclide (subscript 2) and having decay constants lambda1 and lambda2, respectively, the number of daughter nuclei at time t is given by the well-known result7

<i>N</i><sub>2</sub>  =  <i>N</i><sub>10</sub>[<i>lambda</i><sub>1</sub>/(<i>lambda</i><sub>2</sub>  –   <i>lambda</i><sub>1</sub>)][exp(–<i>lambda</i><sub>1</sub><i>t</i>)  –  exp(–<i>lambda</i><sub>2</sub><i>t</i>)],

where N10 is the number of parent nuclei at t = 0, the time at which no daughter nuclei are present. For the readily available 137Cs beta decay to an excited state of 137Ba (respective half-lives of 30.2 y and 2.55 m), the much longer parent half-life means that lambda2>>lambda1, so Eq. (3) may now be written as

<i>N</i><sub>2</sub>  =  <i>N</i><sub>2f</sub>[1  –  exp(–<i>lambda</i><sub>2</sub><i>t</i>)],

where the final equilibrium value of N2 is written as N2f = N10lambda1/lambda2.

A constant water flow obtained directly from a faucet was used to fill a leaking reservoir as a model of this radioactive decay of a long-lived parent to a short-lived daughter. This fluid flow experiment may now be modeled as Eq. (4) plus a constant amount of background radiation. The weight of the leaking reservoir as a function of time was again obtained with the Logger Pro software and the data were fit to the equation

<i>W</i><sub>2</sub>  =  <i>W</i><sub>2f</sub>[1  –  exp(–<i>lambda</i><sub>2</sub><i>t</i>)]  +  <i>W</i><sub>2BG</sub>,

where W2f = W10lambda1/lambda2 and W2BG is the initial weight of the fluid and bottle before filling begins. Figure 2 presents both data and a graph of Eq. (5) using the best-fit values for the adjustable parameters of W2f, lambda2, and W2BG. Sliders for these parameters were again employed for instructional purposes, and the final best-fit values were also obtained by the use of the Solver add-in. This fit is in excellent agreement with the data for this example of secular equilibrium, and we disagree with the statement by Greenslade2 that the "analogue breaks down for large times." Although at this point we are only interested in a qualitative agreement between the data and the mathematical model, all best-fit adjustable parameter values are consistent with direct measurements of corresponding quantities.

Figure 2.


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