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Back To Hit List | Previous / Next Document | Issue Table of Contents Obtaining molecular orientation from second harmonic and sum frequency scattering experiments in water: Angular distribution and polarization dependence Journal of Chemical Physics
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Obtaining molecular orientation from second harmonic and sum frequency scattering experiments in water: Angular distribution and polarization dependence

J. Chem. Phys. 132, 234702 (2010); http://dx.doi.org/10.1063/1.3429969

Published 15 June 2010

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Alex G. F. de Beer and Sylvie Roke
Max Planck Institute for Metals Research, Heisenbergstrasse 3, D70569 Stuttgart, Germany
We present a method for determining molecular orientation from second-order nonlinear light scattering experiments. Our modeling shows that there is an optimal angular region, for which the scattering pattern is most sensitive to molecular orientation. We show that molecular orientation can be retrieved from measuring intensities at different polarization combinations, measuring the relative amplitudes of different vibrational modes of the same moiety and by analyzing the shape of the angular scattering pattern. We further show that for C2v and C3v point groups, the asymmetric stretch mode displays a higher sensitivity to molecular orientation than the corresponding symmetric mode. We have implemented the model in an interactive simulation program that may be found at http://www.mf.mpg.de/en/abteilungen/roke/simulation.html. ©2010 American Institute of Physics
History: Received 3 February 2010; accepted 23 April 2010; published 15 June 2010
Digital Object Identifier http://dx.doi.org/10.1063/1.3429969
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KEYWORDS and PACS

Keywords
PACS
  • 42.65.Ky
    Optical frequency conversion; harmonic generation
  • 33.20.Tp
    Vibrational analysis (molecular spectra)
  • 33.15.Bh
    General molecular conformation and symmetry; stereochemistry
  • YEAR: 2010

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PUBLICATION DATA

ISSN:
0021-9606 (print)   1089-7690 (online)
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REFERENCES (53)
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  1. T. F. Heinz, Nonlinear Surface Electromagnetic Phenomena (Elsevier, New York, 1991) Chap. 5, p. 353.
  2. Y. R. Shen, Nature (London) 337, 519 (1989).
  3. H. F. Wang, W. Gan, R. Lu, Y. Rao, and B. H. Wu, Int. Rev. Phys. Chem. 24, 191 (2005).
  4. A. J. Moad and G. J. Simpson, J. Phys. Chem. B 108, 3548 (2004).
  5. C. A. Dailey, B. J. Burke, and G. J. Simpson, Chem. Phys. Lett. 390, 8 (2004).
  6. W. K. Zhang, H. F. Wang, and D. S. Zheng, Phys. Chem. Chem. Phys. 8, 4041 (2006).
  7. C. Hirose, H. Yamamoto, N. Akamatsu, and K. Domen, J. Phys. Chem. 97, 10064 (1993).
  8. R. Lu, W. Gan, B. H. Wu, H. Chen, and H. F. Wang, J. Phys. Chem. B 108, 7297 (2004).
  9. R. Lu, W. Gan, B. H. Wu, Z. Zhang, Y. Guo, and H. F. Wang, J. Phys. Chem. B 109, 14118 (2005).
  10. Q. Du, R. Superfine, E. Freysz, and Y. R. Shen, Phys. Rev. Lett. 70, 2313 (1993).
  11. H. Chen, W. Gan, B. H. Wu, D. Wu, Y. Guo, and H. F. Wang, J. Phys. Chem. B 109, 8053 (2005).
  12. H. Chen, W. Gan, B. H. Wu, D. Wu, Z. Zhang, and H. F. Wang, Chem. Phys. Lett. 408, 284 (2005).
  13. X. Zhuang, P. B. Miranda, D. Kim, and Y. R. Shen, Phys. Rev. B 59, 12632 (1999).
  14. Note that in this manuscript, we denote the molecular tilt angle with “phi” rather than the more commonly used “theta” since theta is reserved for the scattering angle.
  15. H. Wang, E. C. Y. Yan, E. Borguet, and K. B. Eisenthal, Chem. Phys. Lett. 259, 15 (1996).
  16. E. C. Y. Yan, Y. Liu, and K. B. Eisenthal, J. Phys. Chem. B 102, 6331 (1998).
  17. H. F. Wang, E. C. Y. Yan, Y. Liu, and K. B. Eisenthal, J. Phys. Chem. B 102, 4446 (1998).
  18. L. Schneider, H. J. Schmid, and W. Peukert, Appl. Phys. B: Lasers Opt. 87, 333 (2007).
  19. N. Yang, W. E. Angerer, and A. G. Yodh, Phys. Rev. Lett. 87, 103902 (2001).
  20. E. C. Y. Yan and K. B. Eisenthal, J. Phys. Chem. B 103, 6056 (1999).
  21. E. C. Y. Yan and K. B. Eisenthal, Biophys. J. 79, 898 (2000).
  22. Y. Jiang, P. T. Wilson, M. C. Downer, C. W. White, and S. P. Withrow, Appl. Phys. Lett. 78, 766 (2001).
  23. K. B. Eisenthal, Chem. Rev. (Washington, D.C.) 106, 1462 (2006).
  24. S. H. Jen and H. L. Dai, J. Phys. Chem. B 110, 23000 (2006).
  25. R. K. Campen, D. S. Zheng, H. F. Wang, and E. Borguet, J. Phys. Chem. C 111, 8805 (2007).
  26. H. F. Wang, T. Troxler, A. G. Yeh, and H. L. Dai, J. Phys. Chem. C 111, 8708 (2007).
  27. S. H. Jen, G. Gonella, and H. L. Dai, J. Phys. Chem. A 113, 4758 (2009).
  28. S. -H. Jen, H. -L. Dai, and G. Gonella, J. Phys. Chem. C 114, 4302 (2010).
  29. S. Roke, W. G. Roeterdink, J. E. G. J. Wijnhoven, A. V. Petukhov, A. W. Kleyn, and M. Bonn, Phys. Rev. Lett. 91, 258302 (2003).
  30. S. Roke, J. Buitenhuis, J. C. van Miltenburg, M. Bonn, and A. van Blaaderen, J. Phys.: Condens. Matter 17, S3469 (2005).
  31. S. Roke, O. Berg, J. Buitenhuis, A. van Blaaderen, and M. Bonn, Proc. Natl. Acad. Sci. U.S.A. 103, 13310 (2006).
  32. A. G. F. de Beer, H. B. de Aguiar, J. W. F. Nijsen, and S. Roke, Phys. Rev. Lett. 102, 095502 (2009).
  33. S. Roke, ChemPhysChem 10, 1380 (2009).
  34. H. B. de Aguiar, A. G. F. de Beer, M. L. Strader, and S. Roke, J. Am. Chem. Soc. 132, 2122 (2010).
  35. J. Martorell, R. Vilaseca, and R. Corbalan, Phys. Rev. A 55, 4520 (1997).
  36. J. I. Dadap, J. Shan, K. B. Eisenthal, and T. F. Heinz, Phys. Rev. Lett. 83, 4045 (1999).
  37. S. Roke, M. Bonn, and A. V. Petukhov, Phys. Rev. B 70, 115106 (2004).
  38. J. I. Dadap, J. Shan, and T. F. Heinz, J. Opt. Soc. Am. B 21, 1328 (2004).
  39. A. G. F. de Beer and S. Roke, Phys. Rev. B 75, 245438 (2007).
  40. J. I. Dadap, Phys. Rev. B 78, 205322 (2008).
  41. A. G. F. de Beer and S. Roke, Phys. Rev. B 79, 155420 (2009).
  42. J. I. Dadap, H. B. de Aguiar, and S. Roke, J. Chem. Phys. 130, 214710 (2009).
  43. C. Hirose, N. Akamatsu, and K. Domen, J. Chem. Phys. 96, 997 (1992).
  44. C. Hirose, N. Akamatsu, and K. Domen, Appl. Spec. 46, 1051 (1992).
  45. G. J. Simpson and K. L. Rowlen, J. Am. Chem. Soc. 121, 2635 (1999).
  46. S. H. Lee, J. Wang, S. Krimm, and Z. Chen, J. Phys. Chem. A 110, 7035 (2006).
  47. V. Ostroverkhov, K. D. Singer, and R. G. Petschek, J. Opt. Soc. Am. B 18, 1858 (2001).
  48. W. K. Zhang, D. S. Zheng, Y. Y. Xu, H. T. Bian, Y. Guo, and H. F. Wang, J. Chem. Phys. 123, 224713 (2005).
  49. W. Gan, D. Wu, Z. Zhang, R. R. Feng, and H. F. Wang, J. Chem. Phys. 124, 114705 (2006).
  50. G. Ma and H. C. Allen, Langmuir 22, 11267 (2006).
  51. M. J. Shultz, C. Schnitzer, D. Simonelli, and S. Baldelli, Int. Rev. Phys. Chem. 19, 123 (2000).
  52. Y. Rao, Y. S. Tao, and H. F. Wang, J. Chem. Phys. 119, 5226 (2003).
  53. R. Lu, W. Gan, and H. F. Wang, Chin. Sci. Bull. 48, 2183 (2003).

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